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Emissions from combustion of Pure Plant Oil, PPO
Rape seed oil as created by nature is an excellent fuel. It contains no sulphur which is an advantage regarding SO2 and particle emission. Rape seed oil is one example of tri-glycerides, which contains 11-12% oxygen in the molecule structure, which have an advantage for the combustion process. The oxygen content is considered to be the main reason for higher combustion efficiency compensating for less energy content compared to fossil diesel, and it is the reason for the reduction of visible smoke from the combustion.
To obtain good emission results, Pure Plant Oil should meet corresponding fuel standards for plant oil, and it should be combusted in suitable converted and optimised engines.
Germany is the dominating leader in research of Pure Plant Oil as fuel, and a quality standard has been developed, the so called RK-standard, which is developed specially for Raps Seed Oil. Other Plant Oil´s can have other characteristics influencing on the fuel properties.
As mentioned above, rape seed oil as created by nature is an excellent fuel, but can easily be spoiled by wrong processing, handling and storing. But it is quit easy to do it right.
Besides that combustion of PPO is carbon dioxide neutral, all other emission levels can be improved compared to fossil diesel. The only parameter which in general are unchanged is the NOx emission, because it is related to the combustion technology (high temperature and surplus air), and not directly to the fuel composition.
The following shows the emission test of a VW Golf 1.6 IDI and a VW LUPO 1.2 PDI 3L. The tests are made by professional emission test labortory. Nevertheless, the tests results are unoffcicial.
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Emission test results of VW Golf 1.6D year 84, on Diesel and Plantoil Emission test after 70/220-91/441/EWG (EURO 1, small diesel cars) |
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Limits and measured values in
g / km. Comparison in % |
Limits and measured value in % of limits |
|
EURO 1 |
EURO 2 |
EURO 2 (TDI) |
EURO 3 |
EURO 4 |
CO |
Result |
3,16 |
1,00 |
1,00 |
0,64 |
0,50 |
|
Diesel |
1,00 |
31,6 |
100,0 |
100,0 |
156,3 |
200,0 |
|
Plantoil |
0,58 |
18,4 |
58,0 |
58,0 |
90,6 |
116,0 |
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Plantoil comp. to diesel [%] |
-42,0 |
|
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T.HC (hydro carbons) |
Result |
- |
- |
- |
- |
- |
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Diesel |
0,35 |
- |
- |
- |
- |
- |
|
Plantoil |
0,13 |
- |
- |
- |
- |
- |
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Plantoil comp. to diesel [%] |
-62,9 |
|
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NOx |
Result |
- |
- |
- |
0,50 |
0,25 |
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Diesel |
0,53 |
- |
- |
- |
106,0 |
212,0 |
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Plantoil |
0,43 |
- |
- |
- |
86,0 |
172,0 |
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Plantoil comp. to diesel [%] |
-18,9 |
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T.HC+NOx |
Result |
1,13 |
0,70 |
0,90 |
0,56 |
0,30 |
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Diesel |
0,88 |
77,9 |
125,7 |
97,8 |
157,1 |
293,3 |
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Plantoil |
0,56 |
49,6 |
80,0 |
62,2 |
100,0 |
186,7 |
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Plantoil comp. to diesel [%] |
-36,4 |
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PM (particles) |
Result |
0,18 |
0,08 |
0,10 |
0,05 |
0,025 |
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Diesel |
0,12 |
66,7 |
150,0 |
120,0 |
240,0 |
480,0 |
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Plantoil |
0,07 |
38,9 |
87,5 |
70,0 |
140,0 |
280,0 |
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Plantoil comp. to diesel [%] |
-41,7 |
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The results are all very fine, and shows that the vehicle after the conversion even could meet the EURO2 limits on PPO, but not on fossil diesel. All emissions are improved with PPO compared to fossil diesel(430ppm S)
Emission test results of VW LUPO 1.2 PDI year 99, on Diesel and Plantoil Emission test after 70/220-98/89/EG (EURO 3, small diesel cars) |
| Main test results in g/km |
Limit and meassured value in % of limit |
| EURO 2 (IDI) |
EURO 2 (TDI) |
EURO 3 |
EURO 4 |
| CO |
End result |
1,00 |
1,00 |
0,64 |
0,50 |
| a) Diesel, no modification |
0,3648 |
36,5 |
36,5 |
57,0 |
73,0 |
| b) Diesel, with modification |
0,2700 |
27,0 |
27,0 |
42,2 |
54,0 |
| c) Plantoil, with modification |
0,4200 |
42,0 |
42,0 |
65,6 |
84,0 |
| c)Plantoil to b)Diesel [%] |
55,6 |
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| T.HC |
End result |
- |
- |
- |
- |
| a) Diesel, no modification |
0,03 |
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|
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| b) Diesel, with modification |
0,35 |
- |
- |
- |
- |
| c) Plantoil, with modification |
0,13 |
- |
- |
- |
- |
| c)Plantoil to b)Diesel [%] |
-62,9 |
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| NOx |
End result |
- |
- |
0,50 |
0,25 |
| a) Diesel, no modification |
0,229 |
- |
- |
45,8 |
91,6 |
| b) Diesel, with modification |
0,959 |
- |
- |
191,8 |
383,6 |
| c) Plantoil, with modification |
0,896 |
- |
- |
179,2 |
358,4 |
| c)Plantoil to b)Diesel [%] |
-6,6 |
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| T.HC+NOx |
End result |
0,70 |
0,90 |
0,56 |
0,30 |
| a) Diesel, no modification |
0,3468 |
49,5 |
38,5 |
61,9 |
115,6 |
| b) Diesel, with modification |
0,9620 |
137,4 |
106,9 |
171,8 |
320,7 |
| c) Plantoil, with modification |
0,9250 |
132,1 |
102,8 |
165,2 |
308,3 |
| c)Plantoil to b)Diesel [%] |
-3,8 |
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| CO2 |
End result |
- |
- |
- |
- |
| a) Diesel, no modification |
79,30 |
- |
- | |